| 第 40 卷第 6 期 |  | Vol. 40 No. 6 | | 2010 年 12 月 | Dec 2010 |
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所屬欄目：功能材料
木質(zhì)素-蒙脫土復合物代替三角帶底膠中炭黑的應用研究 |
| 曹仲林，廖澤棟，宋青霞，吳芳梅，蘇勝培*
（湖南師范大學(xué) 化學(xué)化工學(xué)院，資源精細化與先進(jìn)材料湖南省高校重點(diǎn)實(shí)驗室，湖南 長(cháng)沙 410081） |
| 摘 要：通過(guò)共沉淀-脫水法制備了木質(zhì)素-蒙脫土復合物填料，并濕法混煉制備了木質(zhì)素-蒙脫土復合物填充三角帶底膠試驗膠。研究了硫磺和促進(jìn)劑的量、天然橡膠（NR）和順丁橡膠（BR）的質(zhì)量比對三角帶底膠試驗膠的硫化特性和力學(xué)性能的影響。并將木質(zhì)素-蒙脫土復合物填充三角帶底膠與炭黑填充的三角帶底膠進(jìn)行了比較。結果表明：增加硫磺和促進(jìn)劑的量，提高了三角帶底膠試驗膠的硬度和300%定伸應力。增加天然橡膠和順丁橡膠的質(zhì)量比提高了三角帶底膠試驗膠的拉伸強度。調整配方后三角帶底膠試驗膠的綜合性能已與N330填充膠料相當。 |
| 關(guān)鍵詞：木質(zhì)素-蒙脫土復合物；三角帶底膠；力學(xué)性能；硫化特性 |
| 中圖分類(lèi)號：TQ333 文獻標識碼：A 文章編號：1009-9212（2010）06-0051-05 |
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| Study on Application of Lignin-montmorillonite Complex in Base Rubber of V-Belt |
| CAO Zhong-lin，LIAO Ze-dong，SONG Qing-xia，WU Fang-mei，SU Sheng-pei *
（College of Chemistry and Chemical Engineering，The key Laboratory of Meticulous Resource and Advanced Materials，Hunan Normal University，Changsha 410081，China） |
| Abstract：A novel rubber filler，lignin-montmorillonite complex，was prepared by co-precipitation and dehydration of the mixture of montmorillonite and black liquor and used in the base rubber of V-belt manufactured by mechanical mixing method. The effects of the contents of sulphur and accelerator and the mass ratio of natural rubber（NR）to cis-1，4-polybutadiene rubber（BR）on the curing characteristics and the mechanical properties of the base rubber of V-belt were studied. The base rubber filled with lignin-montmorillonite complex was compared with a base rubber filled with carbon black. The results showed that the Shore A hardness and 300% modulus of the base rubber were increased as the content of sulphur and accelerator increased，and the tensile strength was increased as the mass ratio of NR to BR increased. After some adjustments of the formulation，the comprehensive properties of the base rubber filled with lignin-montmorillonite could achieve the standards of the base rubber filled with carbon black. |
| Key words：lignin-montmorillonite complex；base rubber of V-belt；mechanical property；curing characteristic |
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基金項目：湖南師范大學(xué)瀟湘學(xué)者啟動(dòng)資金資助課題（化050613）。
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作者簡(jiǎn)介：曹仲林（1986-），男，湖南常寧人，碩士研究生，研究方向：高分子復合材料。（E-mail：zhonglincao@126.com）
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聯(lián) 系 人： 蘇勝培，教授，博士生導師，研究方向：高分子復合材料。（E-mail：sushengpei@gmail.corn）
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收稿日期：2010-12-20
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