| 第 32 卷第 2 期 |  | Vol. 32 No. 2 | | 2002 年 4 月 | Apr 2002 |
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所屬欄目：其它
對叔丁基苯酚催化加氫制備順式對叔丁基環(huán)己醇 |
| 熊前政; 劉智凌; 廖文文; 王曉光; 劉列瓊(湖南化工研究院; 湖北沙隆達集團煤化公司催化劑廠(chǎng); 湖南長(cháng)沙) |
| 摘 要：采用雷尼鎳、Pd/C、Pt/C等為催化劑 ,由對叔丁基酚液相催化加氫合成順式對叔丁基環(huán)己醇。在反應溫度 110～ 130℃ ,反應壓力 5MPa條件下 ,對叔丁基酚轉化率 10 0 % ,對叔丁基環(huán)己醇收率 >98% ,順式對叔丁基環(huán)己醇選擇性 >75 % |
| 關(guān)鍵詞：對叔丁基苯酚; 對叔丁基環(huán)己醇; 催化; 加氫 |
| 中圖分類(lèi)號：TQ233 文獻標識碼：A 文章編號：1009-9212(2002)02-0025-02 |
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| The synthesis of cis-4-Tert-butylcyclohexanol from 4-Tert-butylphenol by Catalytic hydrogenation. |
| Xiong Qian Zheng; et al（Hunan Research Institute of Chemical Industry; Changsha 410007; China）. |
| Abstract：The synthesis of cis 4 tert butylcyclohexanol was studied from 4 tert butylphenol with Ni,Pd/C,Pt/C et al as catalyst by the way of liquid catalytic hydrogenation.The optimun technology Condition were that the reactic temperature was 110～130℃,the reactic pressure was 1～5MPa.The conversion of 4 tert butylphenol was 100%,The yield of 4 tert butylphenolohexanol was over 98%,The selectivity of cis 4 butylcyclohexanol was over 75%. |
| Key words：tert butylcyclohexanol; catalysis hydrogenation |
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收稿日期：2001-11-27
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