| 第 46 卷第 1 期 |  | Vol. 46 No. 1 | | 2016 年 2 月 | Feb 2016 |
|
所屬欄目：功能材料
金屬有機框架負載雜多酸催化丙三醇一步氧化酯化的研究 |
| 郭麗娟1，高 飛2，張德華2，3，雷玉龍3，段易平3，熊澤山3，靳 昕1，周 婷2，祝 潔2
（1. 中國石油化工股份有限公司煉油事業(yè)部，北京 100728；2. 南京理工大學(xué) 化工學(xué)院，江蘇 南京 210094） |
| 摘 要：制備了金屬有機框架（MOFs）負載的雜多酸催化劑，研究了丙三醇一步氧化酯化的反應條件和催化性能。pH=8，負載8%，反應24 h的條件下，丙三醇轉化率48.6%，酯類(lèi)選擇性34.5%。反應過(guò)程綠色溫和，且催化劑可循環(huán)利用，實(shí)現了生物柴油副產(chǎn)物的再生。研究了催化過(guò)程中各個(gè)因素的影響，并討論了MOFs的傳質(zhì)作用，分析丙三醇一步氧化酯化的反應過(guò)程。 |
| 關(guān)鍵詞：丙三醇；氧化酯化；金屬有機框架；傳質(zhì)效應 |
| 中圖分類(lèi)號：TQ2 文獻標識碼：A 文章編號：1009-9212（2016）01-0070-04 |
|
| Study on One-pot Oxidative Esterification of Glycerol with MOF Supported Polyoxometalates as Catalyst |
| JIN Xin1, ZHOU Ting2, ZHU Jie2
(1. SINOPEC Petroleum Refining Department, Beijing 100728, China; 2. School of Chemical Engineering, Nanjing University of Science & Technology, Nanjing 210094, China) |
| Abstract：Polyoxometalates supported by metal-organic frameworks (MOFs) were synthesized and used as catalysts in the one-pot oxidative esterification of glycerol. Reaction conditions were as follows: pH value was 8, catalyst loading was 8%, and the reaction time was 24 hours. A yield of 48.6% was obtained, and the selectivity of esters was 34.5%. The whole process was sustainable and mild, and catalysts could be recycled. The recyling of the by-products of biodiesel could be achieved. Studies on the catalytic factors and mass transfer of MOFs were carried out. The process was analyzed. |
| Key words：glycerol; oxidative esterification; metal-organic frameworks; mass transfer |
|
作者簡(jiǎn)介：靳 新（1977-），女，遼寧鞍山人，工程師，碩士，研究方向：油品研發(fā)與質(zhì)量管理（E-mail：jinxin01@sinopec.com）。
|
收稿日期： 2016-02-1
|
|