| 第 32 卷第 4 期 |  | Vol. 32 No. 4 | | 2002 年 8 月 | Aug 2002 |
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所屬欄目：其它
水揚酸鎳的合成表征及結構分析 |
| 劉衛兵; 李良超(楚源集團華麗染料公司; 荊州師范學(xué)院化學(xué)系; 湖北石首; 434400; 湖北荊州; 434100) |
| 摘 要：用流變相反應法合成了Ni(OH)Sal·H2 O和Ni2 (OH) 2 Sal2 ·H2 O。通過(guò)元素分析、TG、IR、XRD和磁矩對其結構進(jìn)行了分析。結果表明兩個(gè)配合物都屬于單斜晶系 ,其晶胞參數為 ,Ni(OH)Sal·H2 O∶a =13.1179,b =11.36 41,c =9.5 6 0 5 ,β =92 .96 2 ,V =14 2 3.31(97) 3,Z =7,Dcalcd .=1.885 g/cm3,Dexpt=1.85 8g/cm3;Ni2 (OH) 2 Sal2 ·H2 O :a =13.12 17,b =11.35 80 ,c =9.5 5 2 2 ,β =92 .978 ,V =14 2 1.72 (95 ) 3,Z =4 ,Dcalc=2 .0 73g/cm3,Dexp=2 .0 0 0 g/cm3。 |
| 關(guān)鍵詞：水楊酸鎳; 流變態(tài); 合成; 結構分析 |
| 中圖分類(lèi)號：o614.4 文獻標識碼：A 文章編號：1009-9212(2002)04-0044-02 |
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| The Rheological State Synthesis and Characterization And Structural Analysis of Nickel Monosalicylates |
| LIU Wei bing; LI Liang chao.（Depart.of Chem.; Jingzhou Normal College; Hubei Jingzhou; 434100; China） |
| Abstract：Nickel monosalicylates [Ni(OH)(C 6H 4OHCO 2)·H 2O(A) and Ni 2(OH) 2(C 6H 4OHCO 2) 2·H 2O(B)] were synthesized through the rheological phase reaction method.Their structure was characterized by elemental analysis,IR,TG,X ray power diffraction and magnetic moment.XRD indicated that the two complexs are monoclinic crystal system and its crystal cell parameters are respectively,(A)∶a=13.1179,b=11.3634,c=9.5605?,β=92.962,V=1423.31(97)? 3,Z=9,D calcd =1.885g/cm 3,(B)∶a=13.1217,b=11.3580,c=9.552... |
| Key words：nickel salicylates; rheological phase; synthesis; structure analysis |
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基金項目：湖北省教育廳自然科學(xué)基金資助課題(99C069)
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收稿日期：2002-07-20
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