| 第 48 卷第 1 期 |  | Vol. 48 No. 1 | | 2018 年 2 月 | Feb 2018 |
|
所屬欄目：功能材料
聚異丁烯丁二酸酐衍生物合成工藝研究 |
| 趙華平，董 云，李俊杰，杜華善，周桂松
（中國葛洲壩集團易普力股份有限公司，重慶 401121） |
| 摘 要：以氨基酸酯鹽酸鹽、聚異丁烯丁二酸酐（PIBSA）為主要原料，N，N′-二環(huán)己基碳二亞胺（DCC）為催化劑，基礎油為溶劑，經(jīng)反應合成了聚異丁烯丁二酸酐衍生物類(lèi)乳化炸藥用乳化劑�？疾炝税被狨}酸鹽種類(lèi)、基礎油種類(lèi)、反應物配比、反應溫度及反應時(shí)間等因素對乳化劑性能的影響。優(yōu)化反應條件為：以220 N基礎油為溶劑，n（PIBSA）∶n（o-叔丁基-L-絲氨酸甲酯鹽酸鹽）=1.0∶1.1，反應溫度140℃，反應時(shí)間6 h。此合成工藝簡(jiǎn)單，安全可靠，適合工業(yè)化生產(chǎn)。所合成乳化劑臨界乳化劑用量為1 g，乳膠基質(zhì)水溶值為1.26%，適合用于制備乳化炸藥。 |
| 關(guān)鍵詞：聚異丁烯丁二酸酐；O-叔丁基-L-絲氨酸甲酯鹽酸鹽；乳化劑；合成工藝 |
| 中圖分類(lèi)號：TQ423.92 文獻標識碼：A 文章編號：1009-9212（2018）02-0069-04 |
|
| Synthesis of Polyisobutenyl Succinic Anhydride Derivatives |
| ZHAO Hua-ping, DONG Yun, LI Jun-jie, DU Hua-shan, ZHOU Gui-song
(China Gezhouba Group Explosive Co．,Ltd., Chongqing 401121, China) |
| Abstract：Emulsifier for emulsion explosives of polyisobutylene dihydride derivatives was synthesized from amino-acid ester hydrochloride and polyisobutylene succinic anhydride (PIBSA) using N,N'-dicyclohexylcarbodiimide (DCC) as catalyst in base oil. The effects of amino-acid ester hydrochloride type, base oil type, molar ratio of reactants, reaction temperature and reaction time on the properties of emulsifier were investigated. The optimal reaction conditions include n(PIBSA) ∶n(O-tert-butyl-L-serine methyl ester hydrochloride) of 1.0∶1.1, reaction temperature of 140℃ and reaction time of 6 h. This synthetic process was simple, safe and reliable, suitable for industrial production. The critical emulsifier dosage of the title emulsifier was 1 g and the water solubility value of the emulsion was 1.26%, which is suitable for the preparation of emulsion explosive. |
| Key words：polyisobutenyl succinic anydride; O-tert-butyl-L-serine methyl ester hydrochloride; emulsifier; synthesis process |
|
作者簡(jiǎn)介：趙華平（1987-），女，重慶人，工程師，碩士，研究方向：材料工藝研發(fā)（E-mail：758776838@qq.com）。
|
收稿日期：2018-02-04
|
|