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第 48 卷第 3 期Vol. 48 No. 3
2018 年 6 月Jun 2018

所屬欄目:功能材料

堿木質(zhì)素對EVA復合材料力學(xué)性能的影響
汪巧蕾1,2,3,鄭 艷3,丁紀恒3,OBAID Ur Rahman3,余海斌3,呂 瑾2,蘇勝培2* (1. 河源市正德中學(xué),廣東 河源 517000;2. 湖南師范大學(xué) 化學(xué)化工學(xué)院,湖南 長(cháng)沙 410081;3. 中國科學(xué)院寧波材料技術(shù)與工程研究所,浙江 寧波 315201)
摘 要:將兩種不同的堿木質(zhì)素(Lignin A和Lignin B)分別與乙烯-乙酸乙烯酯共聚物(EVA)在轉矩流變儀中共混后,經(jīng)平板硫化儀熱壓成片制得Lignin/EVA復合材料。探究了兩種堿木質(zhì)素的理化性質(zhì)及其對Lignin/EVA復合材料力學(xué)性能的影響。傅里葉紅外光譜分析(FT-IR)表明Lignin A以紫丁香基基本結構單元為主,Lignin B則以愈創(chuàng )木基、紫丁香基基本結構單元為主;Lignin/EVA復合材料的力學(xué)性能測試結果表明Lignin A/EVA復合材料的力學(xué)性能比Lignin B/EVA復合材料的力學(xué)性能好;掃描電子顯微鏡(SEM)測試結果表明Lignin A與EVA的共混相容性較Lignin B與EVA的共混相容性好。
關(guān)鍵詞:堿木質(zhì)素;乙烯-乙酸乙烯酯共聚物;復合材料;力學(xué)性能
中圖分類(lèi)號:TQ322.4  文獻標識碼:A  文章編號:1009-9212(2018)03-0055-06
Effect of Alkaline Lignins on the Mechanical Properties of Lignin/EVA Composites
WANG Qiao-lei1,2,3, ZHENG Yan3,DING Ji-heng3,OBAID Ur Rahman3,YU Hai-bin3, L?譈 Jin2,SU Sheng-pei2* (1. Heyuan Zhengde Middle School, Heyuan 517000, China; 2. College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China; 3. Ningbo Institute of Materials Technologies and Engineering, Chinese Academy of Sciences, Ningbo 315201, China)
Abstract:Alkali lignin (Lignin A or Lignin B) was mixed with ethylene vinyl acetate copolymer (EVA) in a torque rheometer, and the obtained Lignin/EVA composites samples were prepared by hot pressing. The physicochemical properties of two alkali lignins and their effects on the mechanical properties of Lignin/EVA composites were evaluated. Data from Fourier transform infrared spectroscopy (FT-IR) showed that Lignin A was dominated by the basic structural unit of syringa, however, Lignin B was mainly composed of basic units of guaiacyl and syringa; the mechanical properties of Lignin A/EVA composites were better than that of Lignin B/EVA composites; the results of SEM indicated that the compatibility between Lignin A and EVA was better than that between Lignin B and EVA.
Key words:alkali lignin; ethylene vinyl acetate copolymer; composite; mechanical properties
基金項目:生化木質(zhì)素資源化應用開(kāi)發(fā)研究項目(化531220)。
作者簡(jiǎn)介:汪巧蕾(1993-),女,湖南益陽(yáng)人,碩士研究生,研究方向:高分子復合材料(E-mail:758321116@qq.com)。
聯(lián) 系 人:蘇勝培,教授,博士研究生導師(E-mail:sushengpei@yahoo.com)。
收稿日期:2018-06-05
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