| 第 32 卷第 6 期 |  | Vol. 32 No. 6 | | 2002 年 12 月 | Dec 2002 |
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所屬欄目：其它
催化合成肉桂酸異戊酯 |
| 彭建兵; 銀董紅(湖南婁底師范高等專(zhuān)科學(xué)�；�; 湖南師范大學(xué)精細催化合成研究所; 湖南婁底; 417000; 湖南長(cháng)沙; 410081) |
| 摘 要：以苯甲醛為起始原料 ,經(jīng)Perkin反應首先制備肉桂酸 ,然后在不同催化劑作用下經(jīng)酯化反應合成了肉桂酸異戊酯 ,確定了最佳反應物的配料比、催化劑用量等反應條件 ,當對甲苯磺酸的用量為反應體系量的 3% ,酸醇比為 1∶1 3(mol)時(shí) ,可得到 81%的肉桂酸異戊酯 ,并對合成產(chǎn)物的紅外光譜和物理常數進(jìn)行了測定 ,與文獻值相符。 |
| 關(guān)鍵詞：對甲苯磺酸; 肉桂酸; 異戊醇; 催化合成; 肉桂酸異戊酯 |
| 中圖分類(lèi)號：TQ224.4 文獻標識碼：A 文章編號：1009-9212(2002)06-0025-02 |
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| Catalytic Synthesis of Isoamyl Cinnamate |
| PENG Jian-hing; et al. （ Department of Chemistry and Biology; Hunan Loudi normalCollege; Hunan Loudi; 417000; China） |
| Abstract：The catalytic synthesis of isoamyl cinnamate by the esterifi-cation reaction of cinnamate acid and isoamylol in the presence of different acid catalysts was investigated in this paper. It was found that p-toluenesulfonic (PTS) acid was the efficient catalyst , and also the optimum conditions have been established from the ratio of reactants and the amount of catalyst used in the reaction. The yield of isoamyl cinnamate is 81% when the ratio of cinnamate acid and isoamylol was 1:1. 3, over 3% PTS catalyst. T... |
| Key words：phenyl-propenoate; isoamylol; isoamyl 3-phenyl-propenoate; p-toluenesulfonic; catalytic synthesis |
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基金項目：湖南省自然科學(xué)基金資助項目(01JJY3008)
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收稿日期：2002-08-16
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