| 第 52 卷第 6 期 |  | Vol. 52 No. 6 | | 2022 年 12 月 | Dec 2022 |
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所屬欄目：表面活性劑
高雙鍵保護率甲基封端烯丙醇聚醚的合成與反應活性研究 |
| 陳熒杰1，張美軍2，金一豐3，張善炯2，張 靜1
（1. 浙江綠科安化學(xué)有限公司，浙江 紹興 312369；2. 浙江皇馬尚宜新材料有限公司，浙江 紹興 312369；3. 紹興市特種表面活性劑新材料重點(diǎn)實(shí)驗室，浙江 紹興 312300） |
| 摘 要：采用外循環(huán)式噴霧反應釜以烯丙醇聚醚、氫氧化鈉溶液和氯甲烷為原料，合成得到甲基封端烯丙醇聚醚。對甲基封端烯丙醇聚醚合成工藝進(jìn)行了優(yōu)化，考察了醇鹽化試劑、反應物配比、反應溫度、反應時(shí)間等因素對反應的影響，優(yōu)化條件下產(chǎn)品的雙鍵保護率達98.3%，封端率達98.1%。并對產(chǎn)品進(jìn)行反應活性研究，產(chǎn)品的硅氫化反應活性高，變清時(shí)間短，硅氫轉化率達到98.4%。該合成工藝產(chǎn)品質(zhì)量高、成本低，適合工業(yè)化生產(chǎn)。 |
| 關(guān)鍵詞：烯丙醇聚醚；封端率；雙鍵保護率；硅油改性劑 |
| 中圖分類(lèi)號：TQ326.5 文獻標識碼：A 文章編號：1009-9212（2022）06-0046-05 |
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| Synthesis and Reactivity of Methyl-terminated Allyl Polyethers with High Double Bond Retention |
| CHEN Ying-jie1, ZHANG Mei-jun2, JIN Yi-feng3, ZHANG Shan-jiong2, ZHANG Jing1
(1. Zhejiang Lukean Chemical Co., Ltd., Shaoxing 312369, China; 2. Zhejiang Huangma Shangyi New Material Co., Ltd., Shaoxing 312369, China; 3. Shaoxing Key Laboratory of New Materials for Special Surfactants, Shaoxing 312300, China) |
| Abstract：Methyl-terminated allyl polyether was obtained using allyl alcohol polyether, sodium hydroxide solution and chloromethane as raw materials, and an external circulating spray reactor was used. The synthesis process of methyl-terminated allyl polyether was optimized including alkylation reagent, reactant ratio, reaction temperature and reaction time. Under the optimized conditions, the double bond retention rate reached 98.3% and the sealing rate of the product reached 98.1%. The reactivity of the product was studied, and the product had high hydrosilylation activity, short cleaning time, and the silicon hydrogen conversion rate reached 98.4%. The product is of high quality and low cost, which is suitable for industrial production. |
| Key words：allyl alcohol polyether; sealing rate; double bond retention; silicone oil modifier |
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作者簡(jiǎn)介：陳熒杰（1988—），男，浙江上虞人，工程師，研究方向：表面活性劑的合成研究和產(chǎn)業(yè)化（E-mail：279507555@qq.com）。
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收稿日期：2022-11-04
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