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第 53 卷第 1 期Vol. 53 No. 1
2023 年 2 月Feb 2023

所屬欄目:功能材料

耐酸蝕PVC復合材料制備及性能研究
陳朝彬1,熊耀奇1,鐘龍興1,李佩瑛2,3,周隆晉2,3,蘇勝培2,3* (1. 湖南聯(lián)塑科技實(shí)業(yè)有限公司,湖南 寧鄉 410600;2. 湖南師范大學(xué) 化學(xué)化工學(xué)院,湖南 長(cháng)沙 410081;3. 石化新材料與資源精細利用國家地方聯(lián)合工程實(shí)驗室,湖南 長(cháng)沙 410081)
摘 要:使用無(wú)水石膏代替碳酸鈣作為填料,與聚氯乙烯(PVC)共混制備了耐酸蝕PVC復合材料。當無(wú)水石膏添加量為40份時(shí),耐酸蝕PVC復合材料腐蝕度降低為1.63 g/m2,優(yōu)于耐酸蝕PVC腐蝕度要求。該耐酸蝕材料較添加相同份數碳酸鈣的PVC材料相比,熱穩定性增加,開(kāi)始分解溫度提升4 ℃,800 ℃質(zhì)量保留率為碳酸鈣復合材料的1.3倍;拉伸強度為33.80 MPa,提高28.0%;彎曲模量為1 051 MPa,降低13.4%,沖擊強度為8.86 kJ/m2,降低20.0%。
關(guān)鍵詞:無(wú)水石膏;耐酸蝕;腐蝕度
中圖分類(lèi)號:TB332  文獻標識碼:A  文章編號:1009-9212(2023)01-0067-05
Preparation and Properties of Acid Corrosion Resistant PVC Composites
CHEN Chao-bin1, XIONG Yao-qi1, ZHONG Long-xing1, LI Pei-ying2,3, ZHOU Long-jin2,3, SU Sheng-pei2,3* (1. Hunan Liansu Technology Industrial Co., Ltd., Ningxiang 410600, China; 2. College of Chemistry and Chemical Engineering, Hunan Normal University, Changsha 410081, China; 3. National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources, Changsha 410081, China)
Abstract:Acid corrosion-resistant polyvinyl chloride (PVC) composites were prepared using anhydrous gypsum instead of calcium carbonate as the filler. The advantage was that when the loading of filler is 40, the corrosion degree of the acid corrosion resistant PVC composite material was of 1.63 g/m2, lower than the data required for acid corrosion resistant PVC product. Meanwhile, the decomposition temperature was increased by 4 ℃, and the tensile strength was 33.80 MPa, which was increased by 28.0%. But the bending modulus was 1 051 MPa with a reduction of 13.4%, and the impact strength was 8.86 kJ/m2 with a reduction of 20.0%.
Key words:anhydrous gypsum; acid corrosion resistance; corrosion
作者簡(jiǎn)介:陳朝彬(1982—),男,廣東順德人,工程師,研究方向:高分子復合材料研究(E-mail:ccb308@163.com)。
聯(lián) 系 人:蘇勝培,教授,博士生導師,研究方向:高分子復合材料(E-mail:sushengpei@yahoo.com)。
收稿日期:2022-11-07
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