| 第 53 卷第 3 期 |  | Vol. 53 No. 3 | | 2023 年 6 月 | Jun 2023 |
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所屬欄目：功能材料
雙弓形銅卟啉異相和可見(jiàn)光催化降解甲基橙 |
| 沈小蓉，張思維，周再春，劉秋華*
（湖南科技大學(xué) 化學(xué)化工學(xué)院，理論有機化學(xué)與功能分子教育部重點(diǎn)實(shí)驗室，精細聚合物可控制備及功能化應用湖南省重點(diǎn)實(shí)驗室，湖南 湘潭 411201） |
| 摘 要：金屬卟啉是一類(lèi)具有良好光敏性的大環(huán)芳香化合物。以cis-ortho-雙捆扎的雙弓型銅卟啉1-Cu至4-Cu為光催化劑，以平面銅卟啉TPP-Cu為參照，在異相和可見(jiàn)光下催化降解甲基橙。結果表明銅卟啉光催化性能與大環(huán)扭曲有正向相關(guān)性。采用動(dòng)態(tài)紫外-可見(jiàn)吸收光譜手段跟蹤大環(huán)扭曲對銅卟啉光催化性能的影響。 |
| 關(guān)鍵詞：光催化作用；金屬卟啉；分子構型；甲基橙 |
| 中圖分類(lèi)號：X703 文獻標識碼：A 文章編號：1009-9212（2023）03-0047-04 |
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| Heterogeneous and Visible Light-catalyzed Degradation of Methyl Orange by Double-bowed Copper Porphyrins |
| SHEN Xiao-rong, ZHANG Si-wei, ZHOU Zai-chun, LIU Qiu-hua*
(School of Chemistry and Chemical Engineering, Hunan University of Science and Technology， Key Laboratory of Theoretical Organic Chemistry and Functional Molecules, Ministry of Education, Hunan Provincial Key Laboratory of Controllable Preparation and Functional Applications of Fine Polymers，Xiangtan 411201, China) |
| Abstract：Metalloporphyrin is a macrocyclic conjugated aromatic compound with high performance of photosensitivity. The double-bowed copper porphyrins 1-Cu to 4-Cu cis-ortho-distrapped were used as photocatalysts to catalyze the degradation of methyl orange under visible light and heterogeneous condition, and the planar copper porphyrin TPP-Cu was used as a reference. The results showed a positive correlation between the photocatalytic performance of copper porphyrins and the macrocyclic distortion. The effect of macrocyclic distortion on the photocatalytic performance of copper porphyrins was tracked by means of dynamic UV-vis absorption spectroscopy. |
| Key words：photocatalysis; metalloporphyrin; molecular conformation; methyl orange |
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基金項目：湖南省自然科學(xué)基金資助項目（2023JJ30225），湖南省教育廳重點(diǎn)項目（20A195）。
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作者簡(jiǎn)介：沈小蓉（1998—），女，湖南湘西人，碩士研究生，研究方向：有機合成（E-mail：1255402435@qq.com）。
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聯(lián) 系 人：劉秋華，副教授，研究方向：金屬有機化學(xué)（E-mail：liuqiuhua@hnust.edu.cn）。
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收稿日期：2023-05-26
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