| 第 33 卷第 1 期 |  | Vol. 33 No. 1 | | 2003 年 2 月 | Feb 2003 |
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所屬欄目：其它
新型Nb_2O_5催化劑的制備及催化性能的研究 |
| 彭紅建; 李永新; 龔健(中南大學(xué)湘雅醫學(xué)院有機化學(xué)教研室; 湖南師范大學(xué)化學(xué)化工學(xué)院; 410078; 410083) |
| 摘 要：以乙酸和正丁醇催化酯化合成乙酸正丁酯為探針?lè )磻?,對Nb2 O5型催化劑的制備與催化活性進(jìn)行了一系列的研究 ,得出了優(yōu)惠的工藝條件。正丁醇的轉化率達 95 % ,乙酸正丁酯的選擇性 10 0 %。并對催化劑進(jìn)行了一系列的表征 ,發(fā)現其與催化活性能很好地關(guān)聯(lián)。 |
| 關(guān)鍵詞：探針?lè )磻? 五氧化二鈮; 催化劑; 活性; 表征 |
| 中圖分類(lèi)號：TQ426.6 文獻標識碼：A 文章編號：1009-9212(2003)01-0038-02 |
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| An Investigation on Activity and Preparation of Niobium Oxide Catalyst |
| PENG Hong-jian; et al.（Department Organic Chemistry Xiangya Medical College Center South University; Hunan Changsha 410078; China） |
| Abstract：Taking the synthesis of butyl acetate by the catalytic esteritification of acetic acid and butanol as a probe reaction, a series of studies on the prepation of the catalyst and its activity was made. The conversion ration of butanol and selectivity of butyl acetate are 95% and 100%, respectively, in the optimal condition. Using different analysis method for catalyst, relations with reaction is very good. |
| Key words：probe reaction; niobium oxide; catalyst activity; characterization |
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基金項目：湖南省科委重點(diǎn)攻關(guān)項目(項目代號3253)
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收稿日期：2002-10-23
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