| 第 33 卷第 1 期 |  | Vol. 33 No. 1 | | 2003 年 2 月 | Feb 2003 |
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所屬欄目：其它
水熱法四氧化三錳超細粉體的正交實(shí)驗設計及討論 |
| 湯林; 陳權啟; 黃可龍(中南林學(xué)院應化研究所; 中南大學(xué)化學(xué)化工學(xué)院; 湖南長(cháng)沙; 410003; 410083) |
| 摘 要：以乙醇和高錳酸鉀為原料 ,利用水熱法來(lái)制備四氧化三錳超細粉體。討論了反應釜的填充度并以正交實(shí)驗研究和討論反應溫度、反應時(shí)間、反應物濃度、溶液的酸堿性對實(shí)驗結果的影響 ,最終得到反應的優(yōu)惠工藝條件。對所制備的產(chǎn)物進(jìn)行表征 ,經(jīng)XRD進(jìn)行物相分析 ,確認產(chǎn)物為單一相的Mn3O4 ,經(jīng)粒度分析儀、掃描電鏡檢測 ,產(chǎn)物的粒徑為 5 0～ 90nm ,為四方晶狀顆粒且沒(méi)有明顯的團聚現象。 |
| 關(guān)鍵詞：水熱法; 正交實(shí)驗; 添加劑 |
| 中圖分類(lèi)號：TQ137.1+2 文獻標識碼：A 文章編號：1009-9212(2003)01-0028-03 |
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| Orthogonal Design and Discussed of the Hyperfine Trimanganese Tetroxide Powder by the Hydrothermal Method |
| TANG Lin; et al.（Central South Forestry University; Hunan Changsha; 410004; China） |
| Abstract：Superfines Mn 3O 4 was prepared by the hydrothermal method, using ethanol and potassium permanganate as stocks. Based on orthogonal experiment. The influential factors such as temperature, time, concentration and the acid-basic character were investigated. The product was analyzed by X-ray powder diffraction patterns, Scan electron microscope. The result showed that the Mn 3O 4 is single-phase and the particle size is 50～90nm. |
| Key words：hydrothermal method; orthogonal experiment; additive |
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收稿日期：2002-08-01
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