| 第 33 卷第 2 期 |  | Vol. 33 No. 2 | | 2003 年 4 月 | Apr 2003 |
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所屬欄目：其它
SO_4~(2-)TiO_2固體超酸催化合成異丙基萘的研究 |
| 強敏; 林惠珊; 劉興重; 柯昌美; 李莉(武漢科技大學(xué); 湖北武漢; 430081) |
| 摘 要：用SO2 - 4 TiO2 固體超酸為催化劑合成了二異丙基萘 ,生產(chǎn)過(guò)程簡(jiǎn)單、無(wú)污染、無(wú)腐蝕。SO2 - 4 TiO2 固體超酸催化劑較為適宜的制備條件是 :浸酸濃度為 0 5 0mol/L、焙燒溫度為 5 0 0℃。在催化劑用量為 10 %、反應溫度為 160℃、反應時(shí)間為 2 5h的條件下連續兩次使用SO2 - 4 TiO2 超酸催化萘對丙烯的烷基化反應 ,產(chǎn)品中一異丙基萘、二異丙基萘、三異丙基萘的總含量大于 98%。 |
| 關(guān)鍵詞：萘; 丙烯; 異丙基萘; SO2-4TiO2; 固體超酸 |
| 中圖分類(lèi)號：TQ241.5 文獻標識碼：A 文章編號：1009-9212(2003)02-0022-02 |
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| Synthesis of Isopropylnaphthalene with SO_4~(2-)4TiO_2 Solid Superacid as Catalyst |
| QIANG Min etc.（Wuhan University of Science and Technology; Wuhan Hubei; 430081; China） |
| Abstract：SO 2- 4-TiO 2 solid superacid was used as catalyst in the alkylation of naphthalene with propylene to yield isopropylnaphthalene. The process is simple, lacking pollution and erosion. The optimal conditions of SO 2- 4-TiO 2 solid superacid are dipping acid concentration at 0.50?mol/L and calcinations temperature at 500?℃. The solid superacid can be used as catalyst two times in the alkylation of naphthalene, and the total composition of MIPN,DIPN, and TIPN in product is over 98%. When the consumpt... |
| Key words：naphthalene; propylene; isopropylnaphthalene; SO2-4-TiO2; solid superacid |
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收稿日期：2002-08-01
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