| 第 33 卷第 4 期 |  | Vol. 33 No. 4 | | 2003 年 8 月 | Aug 2003 |
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所屬欄目：其它
微波輻射催化合成氯乙酸十六酯的研究 |
| 黃祖良; 何有成(右江民族醫學(xué)院化學(xué)教研室; 廣西百色) |
| 摘 要：研究了在無(wú)水硫酸銅的催化下,利用微波輻射技術(shù)快速合成氯乙酸十六酯的方法及影響反應收率的因素。實(shí)驗優(yōu)惠反應條件為:氯乙酸和十六醇的摩爾比為4∶1,催化劑用量2 0g,微波輻射時(shí)間5min,微波功率729W。平均收率達83.6%。用IR表征了產(chǎn)物的結構。 |
| 關(guān)鍵詞：氯乙酸十六酯; 催化合成; 無(wú)水硫酸銅; 微波輻射 |
| 中圖分類(lèi)號：O623.42+6 文獻標識碼：A 文章編號：1009-9212(2003)04-0018-02 |
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| The Synthesis of Hexadecanol Bischloroacetate with Catalyst under Microwave Irradiation |
| HUANG Zu liang; etc（Depertment of Chemistry; YouJiang Medical College for nationalities GuangXi Baise; 53300; China） |
| Abstract：The hexadecanol bischloroacetate was synthesized fastly with the technique of microwave irradiation with the anhydrous cupric sulfate as catalyst. The optimal reaction conditions are as follows: the mole ratio of hexadecanol and chloroacetic acid is 5∶1(mol/mol), the amount of catalyst 2.0g, the power microwave 729W, the ratiating time of microware 5 min. Under the conditions the yield is 83.6%. The molecular structures of the fatty alcohol chloracetates were characterized by IR. |
| Key words：hexadecanol bischloroacetate; catalyst synthesis; anhydrous cupric sulfate; microwave irradiation |
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收稿日期：2003-02-13
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