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第 33 卷第 6 期Vol. 33 No. 6
2003 年 12 月Dec 2003

所屬欄目:其它

甲基化-β-環(huán)糊精的制備及其對甲基對硫磷和呋喃丹的增溶作用
周細紅; 曾清如; 劉嫦娥; 郭正元(湖南農業(yè)大學(xué)環(huán)境科學(xué)系; 湖南長(cháng)沙)
摘 要:研究了甲基化 β 環(huán)糊精(MCD)的一種簡(jiǎn)單制備方法及其對甲基對硫磷和呋喃丹的增溶作用。實(shí)驗結果表明:MCD水溶液對甲基對硫磷和呋喃丹有明顯增溶效果,在20g/L的MCD溶液中,甲基對硫磷和呋喃丹的溶解度比在純水中分別提高了21.91和4.01倍,增溶作用的大小與MCD的濃度呈線(xiàn)性相關(guān),而且和農藥的疏水性及分子幾何形狀與環(huán)糊精空腔的匹配程度有關(guān)。
關(guān)鍵詞:MCD; 制備; 增溶; 甲基對硫磷; 呋喃丹
中圖分類(lèi)號:X592  文獻標識碼:A  文章編號:1009-9212(2003)06-0043-03
The Synthesis and Impact on the Solubilization of Parathion-Methyl and Carbofuran of Methyl-β-Cyclodextrin
ZHOU Xi hong; etc (Department of Environmental Sciences; Hunan Agricultural University; Changsha Hunan 410128; China)
Abstract:Methyle β cyclodextrin was simply synthesized, and the impacts on the solubilization of methyl parathion and carbofuran were investigated. The result indicated that methyl β cyclodextrin can significantly increase the solubility of parathion methyl and carbofuran. The concentration of parathion methyl and carbofuran respectively increased 21.91 and 4.01 times with 20?g/L methyl β cyclodextrin. The solubility is linear with concentration of methyl β cyclodextrin, and relates the matching degree be...
Key words:methyl-β-cyclodextrin; synthesis; solubilization; pesticides
收稿日期:2003-02-13
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