| 第 34 卷第 2 期 |  | Vol. 34 No. 2 | | 2004 年 4 月 | Apr 2004 |
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所屬欄目：其它
三光氣法合成N-硝基-N-(2,4,6-三氯苯基)氨基甲酰氯 |
| 李雪祥; 盛平安(勝利油田孤島化工公司化工三廠(chǎng); 華中農業(yè)大學(xué)理學(xué)院化學(xué)系; 山東東營(yíng); 湖北武漢) |
| 摘 要：用三光氣法合成了N 硝基 N (2,4,6 三氯苯基)氨基甲酰氯,并進(jìn)行了結構表征。結果表明,用三氯甲基碳酸酯代替光氣合成該化合物反應安全,條件溫和,選擇性好,收率高,消除了光氣的危險性。 |
| 關(guān)鍵詞：三光氣; N-硝基-N-（2; 4; 6-三氯苯基）氨基甲酰氯; 合成 |
| 中圖分類(lèi)號：TQ225.22 文獻標識碼：A 文章編號：1009-9212(2004)02-0033-02 |
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| Synthesis of N-nitro-N-(2,4,6-trichlorophenyl) carbamic Chloride by BTC |
| LI Xue-xiang~1; SHENG Pin-an~2 （1.Gudao Chemical Industry Corporation Shengli Oilfield Co. Ltd.; Dongying 257231; China; 2.Huazhong Agricultural University; Wuhan 430070; China） |
| Abstract：N-nitro-N-(2,4,6-trichlorophenyl)carbamic chloride were synthesized through non-phosgene method. Their structures were confirmed by elemental analysis, IR as well as ~1HNMR spectroscopy. The experiment showed the way with bis(trichloromethyl)carbonate insted of phosgene can avoid the poison of phosgene. |
| Key words：BTC N-nitro-N-（2; 4; 6-trichlorophenyl）arbamic chloride; synthesis |
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收稿日期：2003-11-24
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