| 第 34 卷第 2 期 |  | Vol. 34 No. 2 | | 2004 年 4 月 | Apr 2004 |
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所屬欄目：其它
不對稱(chēng)取代4-甲基-2,2′-聯(lián)吡啶的制備和分析 |
| 羅爭; 胡濬喆; 林保平(東南大學(xué)化工系; 江蘇南京) |
| 摘 要：分別以4 甲基吡啶、2 溴吡啶為原料,再與相應的溴化吡啶反應,在零價(jià)鈀催化劑作用下,采用still炭 炭偶合成鍵反應制備目標產(chǎn)物,并用化學(xué)計算分析了影響產(chǎn)率的因素,并用紅外光譜、質(zhì)子核磁共振譜等手段對化合物進(jìn)行了表征。 |
| 關(guān)鍵詞：4-甲基吡啶; Stille反應; 4-甲-基2; 2′-聯(lián)吡啶; 電荷 |
| 中圖分類(lèi)號：TQ253.2 文獻標識碼：A 文章編號：1009-9212(2004)02-0022-03 |
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| The Synthesis and Analysis of Unsymmetrically 4-Methyl-2,2′-Bipyridines |
| LUO Zheng; HU Jun-zhe; LIN Bao-ping （Chemistry Department of Southeast University; Nanjing 210096; China） |
| Abstract：The unsymmetrically 4-methyl-2,2′-bipyridines were synthesized from two material. The one was 2-bromine-pyridine and the other was 4-methyl-pyridine, which reacted with bromized-pyridine to get the title compoudns using Pd(O) as catalyst. The structure of the compound was proved by NMR and IR. |
| Key words：4-methyl-pyridine; Stille reaction; 4-methyl-2; 2′-bipyridine; charge |
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收稿日期：2003-10-16
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