| 第 35 卷第 2 期 |  | Vol. 35 No. 2 | | 2005 年 4 月 | Apr 2005 |
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所屬欄目：其它
4-羥基-4′-氰基聯(lián)苯的合成研究 |
| 伍全紅; 肖志海(湖南天宇農藥化工集團有限公司; 南華大學(xué)化學(xué)化工學(xué)院; 湖南衡陽(yáng)) |
| 摘 要：以4羥基聯(lián)苯為原料,經(jīng)過(guò)酯化、傅克�；磻�、氨解、水解和脫水反應等步驟,合成制得液晶材料中間體4羥基4′氰基聯(lián)苯。此合成方法操作簡(jiǎn)單,各步反應條件溫和,總收率為47.7%,不產(chǎn)生含氰廢水,有利于工業(yè)生產(chǎn)。 |
| 關(guān)鍵詞：4-羥基-4′-氰基聯(lián)苯; 4-羥基聯(lián)苯; 液晶; 合成 |
| 中圖分類(lèi)號：O625.67 文獻標識碼：A 文章編號：1009-9212(2005)02-0048-02 |
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| Study on the Synthesis of 4-Hydroxy-4′-Cyano-Biphenyl |
| WU Quan-hong ~（1）; XIAO Zhi-hai~（2）（1. Hunan Tianyu Pesticide Chemical Industry Group Co.; Ltd; Hengyang 421001; China; 2. School of Chemistry and Chemical Engineering; Nanhua University; China） |
| Abstract：hydroxy-4′-cyano-biphenyl could be synthesized by esterification(to protect hydroxyl), F-C reaction, ammonolysis, hydrolysation and dehydration of 4-hydroxy- Biphenyl. In comparison with the other synthetic routes, the operation was easy to be operated, and the yield was proved(the whole yield was 47.7%). And it was easy for manufacture. |
| Key words：4-hydroxy -4′-cyano-biphenyl 4-hydroxy-biphenyl; liquid crystal; synthesis |
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收稿日期：2004-03-26
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