| 第 35 卷第 2 期 |  | Vol. 35 No. 2 | | 2005 年 4 月 | Apr 2005 |
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所屬欄目：專(zhuān)論與綜述
超臨界流體在有機合成中的應用新進(jìn)展 |
| 張現斌; 梁發(fā)書(shū); 鄒長(cháng)軍(西南石油學(xué)院化學(xué)化工學(xué)院; 四川成都) |
| 摘 要：綜述了超臨界流體應用于有機合成的新成果及新動(dòng)向,包括催化氫化、Diels-Alder反應、烯鍵易位反應、環(huán)化反應、費托合成、傅克烷基化反應、酯化反應、氧化反應、烷基化反應、重排反應和水解反應等方面。它在綠色化學(xué)反應方面具有很大的潛在優(yōu)勢。 |
| 關(guān)鍵詞：超臨界流體; 有機合成; 綠色化學(xué)反應 |
| 中圖分類(lèi)號：TQ028.32 文獻標識碼：A 文章編號：1009-9212(2005)02-0001-05 |
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| The Review of Organic Synthesis under Supercritical Condition |
| ZHANG Xian-bin; LIANG Fa-shu; ZOU Chang-jun （College of Chemistry and Chemical Engineering; Southwest Petroleum Institute; Chengdu 610500; China） |
| Abstract：The recent achievements in application of supercritical fluids, as a new reaction system in organic synthesis ,such as catalytic hydrogenation, Diels-Alder reaction, cyclic reaction, Fischer-Tropsch reaction, Friedel-Crafts reaction, esterification, oxidation, alkylation, arrangement, hydrolysis etc. were reviewed. Many references of latest ten years were covered. It has great potential application in green chemical reaction. |
| Key words：supercritical fluids; organic synthesis; green chemical reaction |
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基金項目：四川省重點(diǎn)實(shí)驗室項目(S0005)
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收稿日期：2004-11-26
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