| 第 35 卷第 3 期 |  | Vol. 35 No. 3 | | 2005 年 6 月 | Jun 2005 |
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所屬欄目：分析與測試
1-(2-溴乙氧基)-2-甲基苯異構體的氣相色譜分離分析 |
| 蔣琴(南京大學(xué)現代分析中心; 江蘇南京) |
| 摘 要：采用毛細管氣相色譜法對1-(2-溴乙氧基)-2-甲基苯位置異構體混合物進(jìn)行分離和測定,比較了四種不同固定液對該類(lèi)物質(zhì)的分離特性,發(fā)現在SE-30(50 m×0.32 mm×0.25μm)非極性毛細管柱上鄰、間、對三種位置異構體分離度較好,達到基線(xiàn)分離;采用峰面積歸一化法定量,相對標準偏差在0.084%~1.19%。 |
| 關(guān)鍵詞：氣相色譜; 分離; 1-（2-溴乙氧基）-2-甲基苯; 異構體 |
| 中圖分類(lèi)號：TQ241.1 文獻標識碼：A 文章編號：1009-9212(2005)03-0060-03 |
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| Separation of Position Isomers of 1-(2-bromo-ethoxy)-2-methyl-benzen by Capillary Gas Chromatography |
| JIANG Qin（ Center of materials analysis; Nanjing University; Nanjing 210093; China） |
| Abstract：The GC method for separation and determination of position isomers of 1-(2-bromo-ethoxy)-2-methyl-benzene is introduced. Separation effect of the four different stationary phase capillary column is compared. Best resolution is obtained on SE-30(50 m×0.32 mm×0.25 μm) non-polarity column. The compounds were quantified by normalization method. The relative standard deviation was between 0.084%~1.19%. |
| Key words：capillary gas chromatograph; separation; 1-（2-bromo-ethoxy）-2-methyl-benzene |
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收稿日期：2005-01-29
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