| 第 35 卷第 3 期 |  | Vol. 35 No. 3 | | 2005 年 6 月 | Jun 2005 |
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所屬欄目：其它
聚丙烯酸鋰/鋰鹽聚合物電解質(zhì)的研究 |
| 盧翠紅; 陳平; 董君英; 李麗峰(長(cháng)沙理工大學(xué)化學(xué)與環(huán)境工程系; 湖南長(cháng)沙) |
| 摘 要：以丙烯酸和氫氧化鋰為原料用溶液聚合法合成聚丙烯酸鋰(PAALi),將其熔于低共熔鹽(一定比例的LiNO3-LiOOCCH3混合物)中得到新型高分子固體電解質(zhì)(SPE),用IR技術(shù)進(jìn)行了表征,討論了影響合成PAALi工藝及新型固體電解質(zhì)電導率的主要因素,在Li-NO3-LiOOCCH3質(zhì)量比為1∶1時(shí),將其按質(zhì)量百分比80∶20與聚丙烯酸鋰混合均勻并熔融,得到的電解質(zhì)其室溫離子電導率可達2×10-5S.cm-1. |
| 關(guān)鍵詞：聚合物電解質(zhì); 離子電導率; 鋰離子電池 |
| 中圖分類(lèi)號：TQ317 文獻標識碼：A 文章編號：1009-9212(2005)03-0046-03 |
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| Synthesis and Identification of Electrolyte of poly(lithium acrylate)/lithium salts polymer |
| LU Cui-hong; CHEN Ping; DONG Jun-ying; LI Li-Feng（Changsha University of Science and Technology; Changsha 410077; China） |
| Abstract：The results of preliminary studies of a new polymer electrolyte based on poly(lithium acrylate)-PAALi, with low-melting-point eutectic lithium salts consisted of lithium nitrate and lithium acetate were described. The solution polymerization of PAALi was prepared from crylic acid and LiOH under optimum conditions of initiator concentration 0.2%(w%), monomer concentration 16%(w%), polymerization time 2 h, polymerization temperature 80℃. The ionic conductivity of PAALi was measured at range of 10~(-9)~10~(-10... |
| Key words：polymer electrolyte; ionic conductivity; lithium-ion batteries |
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收稿日期：2005-04-10
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