| 第 35 卷第 3 期 |  | Vol. 35 No. 3 | | 2005 年 6 月 | Jun 2005 |
|
所屬欄目：其它
Fe-Al復合催化合成鄰氯苯胺 |
| 周瑩; 葉翠層; 李水芳; 李林; 孫漢洲(中南林學(xué)院應用化學(xué)研究所; 湖南株洲) |
| 摘 要：研究了Fe-Al復合催化劑催化水合肼選擇性還原硝基制備鄰氯苯胺的條件。結果表明:Fe-Al復合催化劑催化水合肼還原硝基的選擇性≥99%;還原反應的溫度為70℃,物料比為n(鄰氯硝基苯)∶n(水合肼)=1.0∶1.8,鄰氯苯胺的收率為92.91%,ω(鄰氯苯胺)≥99.5%。在工業(yè)上具有更廣泛的應用價(jià)值。 |
| 關(guān)鍵詞：Fe-Al復合催化劑; 水合肼; 選擇性; 還原; 鄰氯硝基苯; 鄰氯苯胺 |
| 中圖分類(lèi)號：TQ246.3 文獻標識碼：A 文章編號：1009-9212(2005)03-0040-02 |
|
| Synthesis of 2-Chloroaniline by Fe-Al Complex as Catalyst |
| ZHOU Ying; YE Cui-ceng; LI Shui-fang; LI Lin; HU Yun-chu; SUN Han-zhou（Research Institute of Applied Chemistry; Central South Forestry University; Zhuzhou 412006; China） |
| Abstract：2-Chloroaniline,which is an important chemical intermediate,was synthesized from 2-Chloroaniline with hydrazine hydrate by using Fe-Al complex as catalyst. The results showed that the selectivity of the catalytic reaction is over 99%. The reaction temperature was 70℃. The mole ratio was n(1-chloro-2-nitrobenzene):n(hydrazine hydrate)= 1.0:1.8. The yield and content of 2chloroaniline are 93.7% and 99.5%. |
| Key words：Fe-Al complex catalyst; hydrazine hydrate; selectivity; reduction; 2-chloro-1-nitrobenzene; 2-chloroaniline |
|
基金項目：湖南省教育廳項目(04C694);中南林學(xué)院科技基金項目(0480)
|
收稿日期：2005-02-25
|
| 閱讀全文 |
|