| 第 35 卷第 3 期 |  | Vol. 35 No. 3 | | 2005 年 6 月 | Jun 2005 |
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所屬欄目：其它
過(guò)氧化氫氧化法合成四氯苯醌的研究 |
| 申利群; 尹篤林; 吳志鴻; 莫洪波(河池學(xué)院化生系; 湖南師范大學(xué)精細催化合成研究所; 廣西宜州; 湖南長(cháng)沙) |
| 摘 要：以對苯二酚,過(guò)氧化氫,鹽酸為原料,以鹽酸與醋酸(比例為2∶3)為溶劑,間歇滴加過(guò)氧化氫,階梯程序升溫反應,反應分別在45℃、70℃、95℃三階段進(jìn)行,原位生成氯氣氯化合成四氯苯醌。合成四氯苯醌的收率和純度都可達97% |
| 關(guān)鍵詞：四氯苯醌; 過(guò)氧化氫; 新方法 |
| 中圖分類(lèi)號：TQ014 文獻標識碼：A 文章編號：1009-9212(2005)03-0017-02 |
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| Synthesis of Chloranil by Hydrogen Peroxide |
| SHEN Li-qun~（1）; YIN Du-lin~（2）; WU Zhi-hong~（1）; MO Hong-bo~（2） （1. Department of Chemistry and Biology; Hechi University; Yizhou 546300; China; 2.Institute of Fine Catalysis and Synthesis; Hunan Normal University; Changsha 410081; China） |
| Abstract：Chloranil was prepared by quinol hydrogen peroxide with hydrochloric acid using hydrochloric acid and acetic acid (2∶3,v/v) as a solvent, programmed heat up, and intermittently adding hydrogen peroxide. Chloranil was synthesized by chloridization in situ, reaction was proceed on three phase according to reactive temperature 45、70、95 ℃. The yield and purity of chloranil reached over 97%. It provided a new measure for preparing chloranil. |
| Key words：chloranil; hydrogen peroxide; new measure |
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收稿日期：2004-11-01
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