| 第 35 卷第 3 期 |  | Vol. 35 No. 3 | | 2005 年 6 月 | Jun 2005 |
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所屬欄目：其它
MCM-41負載Lewis酸催化合成2-甲基吲哚 |
| 莫衛民; 胡仙超; 孫楠; 胡寶祥; 沈振陸(浙江工業(yè)大學(xué)化材學(xué)院; 浙江杭州) |
| 摘 要：以苯肼和丙酮為原料,在負載有各種Lewis酸的MCM-41分子篩催化下采用Fischer吲哚合成法合成2-甲基吲哚,在比較了AlCl3/MCM-41、ZnCl2/MCM-41和FeCl3/MCM-41對反應的選擇性和收率后發(fā)現,負載量為4mmol/g的ZnCl2/MCM-41具有對反應較好的選擇性,目標產(chǎn)物收率達到了76.2%。 |
| 關(guān)鍵詞：分子篩; MCM-41; ZnCl2; AlCl3; 2-甲基吲哚 |
| 中圖分類(lèi)號：O643.36 文獻標識碼：A 文章編號：1009-9212(2005)03-0007-02 |
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| Synthesis of 2-Methylindole over MCM-41 Supported Lewis Acids |
| MO Wei-min; HU Xian-chao; SUN Nan; HU Bao-xiang; SHEN Zhen-lu（Zhejiang University of Technology; Hangzhou 310014; China） |
| Abstract：The 2-methylindole was synthesized by cyclization reaction from phenylhydrazine and acetone catalyzed by MCM-41 molecular sieves, which were supported ZnCl_(2) and other Lewis acids. Among AlCl_(3)/MCM-41, ZnCl_(2)/MCM-41 and FeCl_(3)/MCM-41 catalysts, ZnCl_(2)/MCM-41 which loading 4mmol/g show the best selectivity for the reaction, the yield of the product is 76.2%. |
| Key words：molecular sieves; MCM-41; ZnCl_（2）; AlCl_（3）; 2-methylindole |
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收稿日期：2005-01-14
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