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第 35 卷第 4 期Vol. 35 No. 4
2005 年 8 月Aug 2005

所屬欄目:功能材料

SEBS接枝MAH改性PA6物理性能研究
葉強; 張愛(ài)民; 周燎原(巴陵石油化工有限責任公司合成橡膠事業(yè)部; 四川大學(xué)國家高分子材料與工程重點(diǎn)實(shí)驗室; 湖南岳陽(yáng); 四川成都)
摘 要:研究了PA6/SEBS和PA6/SEBS-g-MAH共混體系與PA6/SEBS/SEBS-g-MAH三元共混體系的力學(xué)性能與流變性能變化。結果表明,采用SEBS增韌尼龍6,控制SEBS和SEBS-g-MAH的比例,在SEBS總量為20%時(shí)能夠制得超韌性的尼龍6,缺口沖擊強度可達到90kJ/m2以上。PA6/SEBS表現出不相容共混體系的流變行為,PA6/SEBS-g-MAH共混體系高于共混物中任一組分的粘度,反映出共混后增強了兩相的界面相互作用。三元共混體系的粘度表現為SEBS和SEBS-g-MAH共同作用結果。
關(guān)鍵詞:SEBS; 改性; MAH; 物理性能
中圖分類(lèi)號:TQ330.7  文獻標識碼:A  文章編號:1009-9212(2005)04-0063-04
Study on the Physical Properties of SEBS-g-MAH Modifying PA6
YE qiang1; ZHANG Ai-ming2; ZHOU Liao-yuan1 (1. Synthetic Rubber Plant Baling Petrochemical CO.; Ltd; Yueyang 414014; China; (2. Research institute of Polymer materials and Engineering Sichuan university; Chendu 610065; China)
Abstract:Mechanical and rheological properties have been investigated of PA6/SEBS blends ,PA6/SEBS-g-MAH blends and PA6/SEBS/SEBS-g-MAH blends in this paper. The results showed that touchening PA6 is available and the impact strength was above 90 KJ/m2 when the total amount of SEBS is 20% adopting SEBS modifying PA6.PA6/SEBS blends act as imcompatibility rheology ,PA6/SEBS-g-MAH have the highest viscosity among the blends,the action of interphase is strengthened after blending.Viscosity of PA6/SEBS/SEBS-g-MAH is the...
Key words:SEBS; modification; MAH; physical properties
基金項目:國家“863”資助項目(No2003AA333020)
收稿日期:2005-04-08
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