| 第 35 卷第 4 期 |  | Vol. 35 No. 4 | | 2005 年 8 月 | Aug 2005 |
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所屬欄目：染料、顏料及涂料
銅酞菁聚甲基丙烯酸甲酯的合成與表征 |
| 鄧建成; 殷煥順; 周燕; 張海良(湘潭大學(xué)化學(xué)學(xué)院; 湖南湘潭) |
| 摘 要：以氯甲基化銅酞菁為引發(fā)劑,過(guò)渡金屬鹵化物和配位劑(Cu2Cl2/2,2`-聯(lián)吡啶)為催化體系,進(jìn)行甲基丙烯酸甲酯原子轉移自由基聚合反應,合成出了銅酞菁聚甲基丙烯酸甲酯,并對其進(jìn)行了結構表征。 |
| 關(guān)鍵詞：銅酞菁; 氯甲基化; 原子轉移自由基聚合 |
| 中圖分類(lèi)號：TQ225.24 文獻標識碼：A 文章編號：1009-9212(2005)04-0039-03 |
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| Synthesis and Characterization of Copper Phthalocyanine-end-capped poly [Methyl methacrylate] |
| DENG Jian-cheng; YIN Huan-shun; ZHOU Yan; ZHANG Hai-liang （College of chemistry of Xiangtan University; Xiangtan 411105; China） |
| Abstract：A novel copper phthalocyanine-end-capped poly[methyl methacrylate] was synthesized by atom transfer radical polymerization (ATRP) using chloromethylate copper phthalocyanine as an initiator and CuBr/2,2-bipydrine as a catalyst. The structure and molecular weight of the copper phthalocyanine PMMA was confirmed by GPC, IR and UV/VIS spectrum. |
| Key words：Copper phthalocyanine-end-capped poly[Methyl methacrylate]; chloromethylation; atom transfer radical polymerization |
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收稿日期：2005-03-02
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