| 第 35 卷第 4 期 |  | Vol. 35 No. 4 | | 2005 年 8 月 | Aug 2005 |
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所屬欄目：專(zhuān)論與綜述
苯酐法合成蒽醌固體酸催化劑的進(jìn)展 |
| 康曉麗; 歐陽(yáng)福生(華東理工大學(xué)石油加工研究所) |
| 摘 要：蒽醌(AQ)是重要的有機合成中間體,采用固體酸催化劑代替傳統的液體酸催化劑可以使蒽醌合成過(guò)程綠色環(huán)保。筆者對固體酸催化劑硅-鋁酸鹽、粘土礦物、金屬氧化物、分子篩、雜多酸催化劑、陽(yáng)離子交換樹(shù)脂應用于蒽醌合成的研究進(jìn)展進(jìn)行了綜述,認為固體酸催化劑對蒽醌合成有很好的研究前景。 |
| 關(guān)鍵詞：蒽醌; 苯酐法; 固體酸催化劑; 鄰苯甲�；郊姿� |
| 中圖分類(lèi)號：TQ244.6 文獻標識碼：A 文章編號：1009-9212(2005)04-0004-04 |
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| Development of Solid Acid Catalysts in Anthraquinone Synthesis with Phthalic Anhydride and Benzene |
| KANG Xiao-li; OUYANG; Fu-sheng （Research Institute of Petroleum Processing; East China University of Science and Technology（ECUST）; Shanghai 200237; China） |
| Abstract：Anthraquinone (AQ) was an important organic synthetic intermediate. Replacing the traditional liquid catalysts with solid acid catalysts would make the process environmentally benign. The development and prospective study of solid acid catalysts in AQ synthesis, such as silica-alumina, acid clays, metal oxides, molecular sieve, heteropoly acid and cation-exchange resin were reviewed in this paper. |
| Key words：anthraquinone; phthalic anhydride process; solid acid catalyst; 2-benzoylbenzoic acid |
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收稿日期：2005-01-24
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