| 第 35 卷第 4 期 |  | Vol. 35 No. 4 | | 2005 年 8 月 | Aug 2005 |
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所屬欄目：專(zhuān)論與綜述
乙苯催化氧化合成苯乙酮研究進(jìn)展 |
| 李家其; 郭軍; 尹篤林(湖南師范大學(xué)化學(xué)化工學(xué)院; 湖南人文科技學(xué)院化學(xué)系; 湖南長(cháng)沙410081湖南人文科技學(xué)院化學(xué)系; 湖南婁底; 湖南長(cháng)沙) |
| 摘 要：綜述了乙苯催化氧化合成苯乙酮的研究進(jìn)展,介紹了雜多化合物、過(guò)渡金屬絡(luò )合物、金屬原子簇化合物、金屬卟啉化合物及分子篩催化劑對乙苯選擇氧化反應的催化效果和特點(diǎn)。結果表明,鉬釩磷雜多化合物及鈷絡(luò )合物是乙苯催化氧化反應的理想催化劑,具有良好的應用前景。 |
| 關(guān)鍵詞：乙苯; 催化; 氧化; 苯乙酮 |
| 中圖分類(lèi)號：TQ244 文獻標識碼：A 文章編號：1009-9212(2005)04-0001-03 |
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| Progress on Ethylbenzene Catalytic Oxidation to Synthesize Acetophenone |
| LI Jia-qi1; 2; GUO Jun 2; YIN Du-lin （1.College of Chemistry and Chemical Engineering; Hunan Normal University; Changsha 410081; China; 2.Department of chemistry; Hunan Humanities Science and Technology College; Loudi 417000; China） |
| Abstract：The research development on behaviors of ethylbenzene catalytic oxidation to synthesize acetophenone was reviewed.The functions and characteristic of catalysts in selective oxidation of ethylbenzene were described for heteropoly compound, transition metal complex, transition metal compound, metal cluster compound,metalloporphyrin compound and molecular sieve catalyst.The results showed that the molybdovanado phosphate heteropoly compound and cobalt complex were good catalysts for the catalytic oxidation of ... |
| Key words：ethylbenzene; catalyst; oxidition; acetophenone |
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收稿日期：2005-03-22
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