| 第 35 卷第 5 期 |  | Vol. 35 No. 5 | | 2005 年 10 月 | Oct 2005 |
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所屬欄目：有機合成原料
溶劑法醇解合成3,3,3-三氟丙基甲基二甲氧基硅烷 |
| 朱淮軍; 何孟芬(南昌大學(xué)化學(xué)系; 廣州化學(xué)試劑廠(chǎng); 江西南昌; 廣東廣州) |
| 摘 要：以3,3,3-三氟丙烯與甲基二氯硅烷催化合成3,3,3-三氟丙基甲基二氯硅烷。采用 溶劑法,以3,3,3-三氟丙基甲基二氯硅烷和甲醇為原料醇解合成3,3,3-三氟丙基甲基二甲氧基 硅烷�？疾烊軇┓N類(lèi)、原料配比、冷凝溫度、填料大小等因素的影響,確立了最優(yōu)合成條件。 |
| 關(guān)鍵詞：3; 3-三氟丙基甲基二甲氧基硅烷; 醇解; 溶劑法; 合成 |
| 中圖分類(lèi)號：TQ264.1 文獻標識碼：A 文章編號：1009-9212(2005)05-0035-03 |
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| Synthesis of Trifluoropropylmethyldimethoxysilane |
| ZHU Huai-jun; HE Meng-fen Chemistry Department of Nanchang University; Nanchang 330047; China; Guangzhou Chemical Reagent Factory; Guangzhou 510288 |
| Abstract：3,3,3-Trifluoropropylmethyldichlorosilane was prepared in the presence of catalyst platinum by addi-tion reaction of trifluoropropene and methyldichlorosilane, and trifluoropropylmethyldirnethoxysilane was synthesized with trifluoropropylmethyldichlorosilane and methanol by solution method. The influence of reaction conditions such as solvent; staple ratio, cooling fluid temperature and filling size were observed. The optimum conditions for synthesizing trifluoropropylmethyldimethoxysilane were established. |
| Key words：3; 3-trifluoropropylmethyldimethoxysilane; alcoholysis; solution method; synthesis |
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收稿日期：2005-05-14
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