| 第 35 卷第 6 期 |  | Vol. 35 No. 6 | | 2005 年 12 月 | Dec 2005 |
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所屬欄目：專(zhuān)論與綜述
二氯化苯基膦的合成進(jìn)展 |
| 謝文杰; 王鑒; 曾群; 曲云龍; 楊年興(大慶石油學(xué)院化學(xué)化工學(xué)院; 天津大學(xué)化工學(xué)院; 大慶石化公司; 黑龍江大慶) |
| 摘 要：簡(jiǎn)要的介紹了苯基二氯化磷的用途及發(fā)展前景,綜述了苯基二氯化磷的合成方法。著(zhù)重從催化機理和反應歷程的角度探討了三氯化鋁催化合成DCPP、離子液體催化合成DCPP、自由基加成反應合成DCPP三類(lèi)合成反應的過(guò)程,并綜述了各類(lèi)反應的進(jìn)展情況及存在的問(wèn)題。尋找一條綠色無(wú)污染,工藝簡(jiǎn)單,操作容易,收率高的合成路線(xiàn),仍然是該領(lǐng)域的熱門(mén)課題。 |
| 關(guān)鍵詞：二氯化苯基膦; 合成機理; 中間體 |
| 中圖分類(lèi)號：TQ265.1 文獻標識碼：A 文章編號：1009-9212(2005)06-0019-03 |
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| Development of the Synthesis of Dichlorophenylphosphine |
| XIE Wen-jie;WANG Jian;ZENG Qun;QUN Yun-long;YANG Nian-xing(Chemistry and Chemical Engineering College;Daqing Petraleum Institute;Daqing 163318;China;Chemical Engineering College;Tianjin University;Tianjin;Daqing Chemical Company SINOPEC; China) |
| Abstract：The application and prospect of dichlorophenylphosphine dichloride were briefly introduced,and the synthetic method of dichlorophenylphosphine dichloride was also described.The processes of preparing DCPP through AlCl3 catalytic synthesis?ionic liquid catalytic synthesis?free radical addition reaction synthesis,were discussed mainly in aspect of the mechanism of catalytic reaction,the existing problems and the progress of the study on the reaction were also discussed.Finding a new simple synthetic process w... |
| Key words：dichlorophenylphosphine; mechanisms of the reaction; intermediate |
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收稿日期：2005-09-21
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