| 第 36 卷第 1 期 |  | Vol. 36 No. 1 | | 2006 年 2 月 | Feb 2006 |
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所屬欄目：專(zhuān)論與綜述
重排反應在精細化工中間體合成中的應用 |
| 孫小軍; 趙衛光; 董衛莉; 李正名(南開(kāi)大學(xué)元素有機化學(xué)國家重點(diǎn)實(shí)驗室元素有機化學(xué)研究所; 淮陰師范學(xué)院化學(xué)系; 江蘇淮安) |
| 摘 要：因為在有機合成中有些反應通過(guò)常規的合成法難以達到預期的目的或比較煩瑣,因此重排反應是一個(gè)行之有效的方法。重排反應具有很高的反應效率,而且具有很高的立體選擇性。本文主要闡述了重排反應在醫藥、農藥、天然產(chǎn)物、染料等合成中的應用。 |
| 關(guān)鍵詞：重排; 有機合成; 應用 |
| 中圖分類(lèi)號：Q621.25+9.3 文獻標識碼：A 文章編號：1009-9212(2006)01-007-04 |
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| Application of Rearrangement Reaction in Organic Synthesis |
| SUN Xiao-jun;ZHAO Wei-guang;DONG Wei-li;LI Zheng-ming(National Key Laboratory of Elemento-Organic Chemistry;Institute of Elemento-Organic Chemistry;Nankai University;Tianjin;Department of Chemistry;Huaiyin Teachers College;Jiangsu Huaian;223001) |
| Abstract：It was very difficult for some reactions in the organic synthesis to carry through via the conventional methods,and more than that,they were very complicated.In those cases,the rearrangement reaction was a feasible method.Rearrangement processes were very effective for organic synthesis because of their high efficiency and high stereo-selectivity.Applications of rearrangement reactions in the pharmaceutics,pesticides,natural products and dyes were reviewed In this paper. |
| Key words：rearrangement; organic synthesis; application |
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基金項目：國家自然科學(xué)基金青年基金資助(20202003)
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收稿日期：2005-11-20
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