| 第 36 卷第 2 期 |  | Vol. 36 No. 2 | | 2006 年 4 月 | Apr 2006 |
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所屬欄目：有機合成原料
二元醇雙琥珀酸雙酯磺酸鈉(GMI-02)的合成 |
| 李小芳; 尹篤林; 曾紀朝; 姚志鋼; 黎小武(邵陽(yáng)學(xué)院生物與化學(xué)工程系; 湖南師范大學(xué)化學(xué)化工學(xué)院; 湖南邵陽(yáng)422000湖南師范大學(xué)化學(xué)化工學(xué)院; 湖南長(cháng)沙; 湖南邵陽(yáng)) |
| 摘 要：采用1,4-丁二醇、馬來(lái)酸酐、月桂醇為主要原料和環(huán)境友好的工藝路線(xiàn),合成了一種易降解的雙子(Gemini)表面活性劑--二元醇雙琥珀酸雙酯磺酸鈉(GMI-02)。對各步合成條件采用正交實(shí)驗進(jìn)行優(yōu)化,得出各步反應的優(yōu)化工藝條件:酯化反應I,配比為n(1,4-丁二醇)∶n(馬來(lái)酸酐)=1∶2.15,反應時(shí)間2h,催化劑w(乙酸鈉)=1.0%,反應溫度95℃,以丙酮作溶劑,回流操作;酯化反應Ⅱ,甲苯為溶劑,反應時(shí)間6h,反應溫度145℃,催化劑w(對甲苯磺酸)=1.0%,n(1,4-丁二醇雙馬來(lái)酸單酯)∶n(月桂醇)=1∶2.20�；腔磻�,石蠟加熱,石蠟溫度(加熱溫度)控制在115℃,時(shí)間為6h,原料配比為n(1,4-丁二醇雙馬來(lái)酸雙酯)∶n(亞硫酸氫鈉)=1∶2.50。對每步合成產(chǎn)物均用IR進(jìn)行了表征。 |
| 關(guān)鍵詞：雙子表面活性劑; 1; 4-丁二醇; 馬來(lái)酸酐; 磺化; 酯化 |
| 中圖分類(lèi)號：TQ423.34 文獻標識碼：A 文章編號：1009-9212(2006)02-0043-04 |
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| Synthesis of Gemini Surfactants Sodium Diol Bisulfosuccinate Dieser(GMI-02) |
| LI Xiao-fang;YIN Du-lin;ZENG Ji-chao;YAO Zhi-gang;LI Xiao-wu(Department of Biological and Chemical Engineering;Shaoyang College;Shaoyang 422000;China;College of Chemistry and Chemical Engineering; Hunan Normal University;Changsha 410081;China) |
| Abstract：A new type of easily degradable Gemini surfactant (GMI-02) was synthesized from cheap materials such as 1,4-butanediol,maleic anhydride and lauric alcohol through environmentally-friendly processes. The optimum reaction conditions were obtained via orthogonal experiments. The first esterification reaction was carried out by refluxing in acetone for 2 h with n(1,4-butanediol) ∶ n(maleic anhydride)=1.00 ∶ 2.15 and 1.0% catalyst sodium acetate. The second esterification reaction was carried out with n(1,4-buta... |
| Key words：Gemini surfactants; 1; 4-butaneliol; maleic anhydride; sulfonation; esterification |
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收稿日期：2005-12-20
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