| 第 36 卷第 3 期 |  | Vol. 36 No. 3 | | 2006 年 6 月 | Jun 2006 |
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所屬欄目：分析與測試
Ziegler-Natta催化劑催化的1-癸烯齊聚物的結構表征 |
| 陽(yáng)小宇(湖南化工職業(yè)技術(shù)學(xué)院; 湖南株洲) |
| 摘 要：采用GC-MS和13C NMR對Ziegler-Natta催化劑催化1-癸烯齊聚所得齊聚物的組成和結構進(jìn)行了表征。GC-MS和GC的分析結果表明所得齊聚物是混合物,主要由二聚體、三聚體、四聚體和五聚體組成。齊聚物的質(zhì)量百分含量分別為14%、45%、31%和10%。13C NMR結果表明1-癸烯齊聚時(shí)存在鍵接異構,除頭-尾鍵接的1,2插入,還存在頭-頭,尾-尾鍵接的2,1插入。1-癸烯齊聚物的傾點(diǎn)低,粘度指數高。 |
| 關(guān)鍵詞：1-癸烯; 齊聚物; 結構; 性能 |
| 中圖分類(lèi)號：TQ314.258 文獻標識碼：A 文章編號：1009-9212(2006)03-0067-03 |
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| Structure and Properties of Oligomer from 1-Decene Catalyzed by Ziegler-Natta Catalyst |
| YANG Xiao-yu（Hunan Chemical Industry Profession and Technology College; Zhuzhou 412004; China） |
| Abstract：The oligomer from 1-decene promoted by Ziegler-Natta Catalyst was characterized with GC-MS,GC and 13C NMR methods.The results from GC-MS and GC analysis confirmed that the oligomer was a mixture consisting of di-(14%),tri-(45%),tetra-(31%) and pentamer(10%).The 13C NMR data also implied that the chain propagation of the oligomer involved primarily head-to-tail 1,2-insertions,as well as head-to-head and tail-to-tail 2,1-insertions.The oligomer obtained featured lower pour point and high viscosity index. |
| Key words：1-decene; oligomer; structure; properties |
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收稿日期：2006-02-19
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