| 第 36 卷第 3 期 |  | Vol. 36 No. 3 | | 2006 年 6 月 | Jun 2006 |
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所屬欄目：功能材料
阻燃劑聚季戊四醇磷酸酯的合成及表征 |
| 郭增山; 朱長(cháng)進(jìn); 劉吉平(北京理工大學(xué)化工與環(huán)境學(xué)院應用化學(xué)系; 北京理工大學(xué)阻燃材料研究國家專(zhuān)業(yè)實(shí)驗室) |
| 摘 要：以季戊四醇、三氯氧磷為原料,采用無(wú)溶劑法首先合成了季戊四醇二磷酸酯二磷酰氯(PDD),n(季戊四醇)n∶(三氯氧磷)=1 5∶,收率為84%;然后以PDD和對苯二酚為原料,乙腈為溶劑,三乙胺為縛酸劑,在氮氣氛圍下合成了低聚阻燃劑聚季戊四醇磷酸酯,n(PDD)∶n(對苯二酚)=1∶1,收率為79%。采用紅外光譜、磷譜、熱重分析和差示掃描量熱法對聚合物的結構和熱行為分別進(jìn)行了表征和研究。結果表明,該聚合物具有較高的玻璃態(tài)轉變溫度(Tg=231℃),聚合物質(zhì)量損失5%時(shí)的溫度為301℃。當聚合物被加熱到600℃時(shí),其炭殘留物的質(zhì)量分數為46.4%。 |
| 關(guān)鍵詞：阻燃劑; 聚季戊四醇磷酸酯; 合成; 玻璃態(tài)轉變溫度; 炭殘留物 |
| 中圖分類(lèi)號：TQ314.24+8 文獻標識碼：A 文章編號：1009-9212(2006)03-0043-03 |
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| Synthesis and Characterization of Flame Retardant Polymeric Pentaerythrityl Phosphate |
| GUO Zeng-shan1; ZHU Chang-jin1; LIU Ji-ping2（1.Department of Applied Chemistry; School of Chemical Engineering and Environment; Beijing Institute of Technology; Beijing 100081; China; 2.National Laboratory of Flame-Retarded Materials; China） |
| Abstract：Pentaerythritol diphosphonate dichloride(PDD)was synthesized in yield 84% from pentaerythritol and phosphorous oxychloride(5equiv.)first in the absence of organic solvent,and then an oligomer polymeric pentaerythrityl phosphate was synthesized in yield 79% from PDD and hydroquinone(1equiv.)using acetonitrile as solvent and triethylamine as acid acceptor under N2 atmosphere.The structure and thermal behaviors of the polymer were characterized and studied by IR,31P NMR,TGA and DSC respectively.The results ind... |
| Key words：flame retardant; polymeric pentaerythrityl phosphate; synthesis; glass transition temperature; char residue |
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收稿日期：2006-01-16
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