| 第 36 卷第 3 期 |  | Vol. 36 No. 3 | | 2006 年 6 月 | Jun 2006 |
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所屬欄目：香精香料
硫酸銅催化合成醋酸環(huán)己酯的研究 |
| 梁學(xué)博; 肖洋; 郭燦城(湖南大學(xué)化學(xué)化工學(xué)院; 湖南長(cháng)沙) |
| 摘 要：分別以濃硫酸、氯化鐵、硫酸銅為催化劑催化合成醋酸環(huán)己酯,考察了有無(wú)結晶水的硫酸銅對酯化反應的影響。在較優(yōu)催化劑CuSO4.5H2O催化下,考察了反應時(shí)間、催化劑用量、醇酸比等因素對酯化率的影響。研究表明,當醇酸摩爾比為1.6∶1,硫酸銅用量對反應物摩爾比為1∶50時(shí),環(huán)己烷作帶水劑,反應2h,酯化率可達96.7%,且催化劑可重復使用。 |
| 關(guān)鍵詞：醋酸環(huán)己酯; 硫酸銅; 催化; 合成 |
| 中圖分類(lèi)號：TQ225.24 文獻標識碼：A 文章編號：1009-9212(2006)03-0037-03 |
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| Catalytic Synthesis of Cyclohexyl Acetate with Copper Sulfate |
| LIANG Xue-Bo; XIAO Yang; GUO Can-Cheng（College of Chemistry and Chemical Engineering; Hunan University; Changsha 410082; China） |
| Abstract：Cyclohexyl acetate was synthesized by oil of vitriol,ferric chloride and copper sulfate,respectively,and the influence of copper sulfate containing water and no-water for the reaction was discussed.The influence of reaction time,dosage of catalyst and molar ratio of cyclohexanol/acid were investigated in the presence of copper sulfate used as catalyst.The results showed that the esterification yield could reach 96.7% when the mole ratio of alcohol/acid was 1.6 ∶ 1,the mole amount of copper sulfate was 1 ∶ 5... |
| Key words：cyclohexyl acetate; copper sulfate; catalysis; synthesis |
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收稿日期：2006-02-20
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