| 第 36 卷第 4 期 |  | Vol. 36 No. 4 | | 2006 年 8 月 | Aug 2006 |
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所屬欄目：香精香料
超聲波引發(fā)格氏反應制備幾種香料 |
| 袁金亮; 甄宏爝(廣州道明化學(xué)有限公司; 廣州百花香料股份有限公司; 廣東廣州) |
| 摘 要：以超聲波為引發(fā)條件,引發(fā)制備格氏試劑,從而制備幾種香料:二甲基芐基原醇、4-甲基-3-癸烯-5-醇、1-辛烯-3-醇、8-烯丙基-8-羥基三環(huán)[5,2,1,02,6]癸烷。與常規引發(fā)條件相比,超聲波引發(fā)格氏反應具有反應時(shí)間短、節約能源、操作簡(jiǎn)便、收率高等優(yōu)點(diǎn)。 |
| 關(guān)鍵詞：合成; 超聲波; 格氏反應; 香料 |
| 中圖分類(lèi)號：TQ655 文獻標識碼：A 文章編號：1009-9212(2006)04-0037-03 |
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| Synthesis of Aromatics by Grignard Reaction with Supersonic Wave as Revulsant |
| YUAN Jin-liang1; ZHEN Hong-jue2（1. Guangzhou Daoming Chemical Co.; Ltd.; Guangzhou 510665; China; 2 . Guangzhou Baihua Flavors & Fragrances Co.; Guangzhou 510370; China） |
| Abstract：Synthesis methods of some aromatics such as dimethylbenzyl carbinol,4-methyl-3-decene-5-ol,1-octene-3-ol,8-allyl-8-hydroxytricyclo[5,2,1,02,6]decane by Grignard reaction were summarized in the paper using supersonic wave as revulsant. This method had characteristics of short reaction time,few energetic resources,simple operation conditions,high yield,and etc compared with the conventional methods. |
| Key words：supersonic wave; Grignard reaction; aromatics; synthesis |
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收稿日期：2006-03-06
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