| 第 36 卷第 5 期 |  | Vol. 36 No. 5 | | 2006 年 10 月 | Oct 2006 |
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所屬欄目：有機合成原料
合成2,3,5-三甲酚催化劑的研究 |
| 顧金泉; 黃晴; 劉純山(華東理工大學(xué)催化研究所) |
| 摘 要：采用等體積浸漬法制備負載型催化劑用于3,5-二甲酚甲基化反應,在固定床反應器中考察了載體的焙燒溫度、助劑、催化劑的焙燒溫度和焙燒時(shí)間等因素對催化劑活性影響分析。結果表明:Fe2O3-Cr2O3/Al2O3催化劑在反應中具有較高的反應活性和選擇性。 |
| 關(guān)鍵詞：3; 5-二甲酚; 2; 5-三甲酚; 甲基化; 鐵催化劑 |
| 中圖分類(lèi)號：TQ426.8 文獻標識碼：A 文章編號：1009-9212(2006)05-0060-03 |
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| Synthesis of 2,3,5-Trimethylphenol over an Iron Catalyst |
| GU Jin-quan; HUANG Qing; LIU Chun-shan（Institute of Catalyzer; East China University of Science & Technology; Shanghai 200237; China） |
| Abstract：Gas-phase alkylation of 3,5-xylenol by methanol over a catalyst containing iron oxide as the main component in a fixed-bed continuous process was studied.The effects of the support grill temperature,Cr content,the calcination temperature and time of catalysts were investigated.By means of some experiments,it was found that the catalysts had good activity and selectivity in the reactivity. |
| Key words：3; 5-xylenol; 2; 5-trimethylphenol; methylation; iron catalyst |
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收稿日期：2006-07-06
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