| 第 36 卷第 6 期 |  | Vol. 36 No. 6 | | 2006 年 12 月 | Dec 2006 |
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所屬欄目：有機合成原料
鄰氯氯芐催化氯化工藝改進(jìn) |
| 曹卓; 吳衛(湖南株洲化工集團有限責任公司技術(shù)中心; 湖南株洲) |
| 摘 要：針對目前國內鄰氯氯芐生產(chǎn)工藝存在的主要問(wèn)題,通過(guò)選用新型催化劑CHJ-3,改進(jìn)催化氯化工藝,使氯化反應鄰氯甲苯轉化率達到60%。與傳統催化劑相比較,氯化反應時(shí)間縮短一倍,反應轉化率提高50%,從而有效地降低了生產(chǎn)成本,經(jīng)濟效益和社會(huì )效益顯著(zhù),具有很好的推廣應用價(jià)值。 |
| 關(guān)鍵詞：鄰氯甲苯; 鄰氯氯芐; 催化氯化; 催化劑 |
| 中圖分類(lèi)號：TQ242 文獻標識碼：A 文章編號：1009-9212(2006)06-0044-04 |
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| An Improvement on Catalytic Chlorination Process of o-Chlorobenzyl Chloride |
| CAO Zhuo; WU Wei（Technical Centre of Hunan Zhuzhou Chemical Industry Group Co.; Ltd.; Zhuzhou 412004; China） |
| Abstract：According to the main problem of current synthesis of o-chlorobenzyl chloride in our country,effective improvement was studied to increase the reaction conversion to 60% by use of a new catalyst CHJ-3.The new catalyst would shorten a half of the reaction time and increased the reaction conversion 50% compared with general catalyst,and reduced the production cost.The results indicated that the improvement had an obvious economic and social benefits,and was worthy of extensions and applications |
| Key words：o-chlorotoluene; o-chlorobenzyl chloride; catalytic chlorination; catalyst |
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收稿日期：2006-07-13
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