| 第 36 卷第 6 期 |  | Vol. 36 No. 6 | | 2006 年 12 月 | Dec 2006 |
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所屬欄目：有機合成原料
間苯二甲酸液相催化氧化合成間苯二酚研究 |
| 崔建新; 肖如亭(天津理工大學(xué)生物與化工學(xué)院) |
| 摘 要：以間苯二甲酸為起始原料,在催化劑銅和助劑鎂作用下,以空氣中的分子氧作氧化劑,通過(guò)液相催化氧化繼而水解制得間苯二酚。通過(guò)系列實(shí)驗考察了溫度、催化劑及助劑用量、空氣流量、攪拌強度、水解條件等因素對反應的影響,確定了反應條件:反應溫度250℃,催化劑用量7%,助劑用量7%,空氣流量0.2L/min,攪拌強度200r/min,水解溫度230℃,水解時(shí)間2h。在此條件下間苯二甲酸轉化率32.3%,間苯二酚收率18.9%。 |
| 關(guān)鍵詞：間苯二甲酸; 催化氧化; 間苯二酚 |
| 中圖分類(lèi)號：O623.1 文獻標識碼：A 文章編號：1009-9212(2006)06-0037-04 |
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| Synthesis of Resorcinol through Liquid-Phase Catalytic Oxidation of Isophthalic Acid |
| CUI Jian-xin; XIAO Ru-ting（School of Biology and Chemical Engineering; Tianjin University of Technology; Tianjin 300191; China） |
| Abstract：Resorcinol was prepared from isophthalic acid through liquid-phase catalytic oxidation and subsequent hydrolysis using oxygen in the air as oxidizing agent in the presence of catalyst copper and promoter manganese.Influences of factors such as reaction temperature,amount of catalyst and promoter,air flow rate,stirring velocity and hydrolytic conditions on the reactions were investigated.The optimal reaction conditions were obtained as follow: reaction temperature 250℃,amount of catalyst Cu 7%,amount of prom... |
| Key words：resorcinol; isophthalic; synthesis |
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基金項目：天津市自然科學(xué)基金資助項目(023606811,033700411)
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收稿日期：2006-09-24
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